Product ID:GLYCINE, 50052
MSDS Date:07/01/1999
FSC:6505
NIIN:00N092438
Status Code:A
MSDS Number: CJRPT

Emergency Phone: 414-273-3850

Info Phone: 414-273-3850

Cage: 63181

Telephone: 414-273-3850

Cage: 63181

(ORAL,RAT) 7930 MG/KG.

CAS: 56-40-6

RTECS: MB7600000

LD50 LC50 Mixture:SEE INGREDIENT & TOXICOLOGICAL INFO.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION OR SKIN ABSORPTION. MAY CAUSE EYE IRRITATION. MAY CAUSE
SKIN IRRITATION. MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND
UPPER RESPIRATORY TRACT.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS
AMOUNTS OF WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE.
INHALATION: REMOV E TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION:
WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL MD.

Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THIS MATERIAL, LIKE MOST MATERIALS IN
POWDER FORM, IS CAPABLE OF CREATING A DUST EXPLOSION. EMITS TOXIC F
UMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP,
PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL S ITE AFTER MATERIAL PICKUP IS
COMPLETE.

Handling and Storage Precautions:AVOID INHALATION. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. KEEP
TIGHTLY CLOSED. STORE IN A COOL, DRY PLACE.

Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MANUFACTURER'S INFORMATION ON INGREDIENTS: MF: C2H5NO2. EC NO:
200-272-2.

Appearance and Odor:WHITE CRYSTALLINE POWDER.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE, NITROGEN OXIDES, AMMONIA.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Toxicological Information:TO THE BEST OF MFR'S KNOWLEDGE, THE CHEMICAL,
PHYSICAL AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY
INVESTIGATED. TOXICITY DATA: LD50:(ORAL,RAT) 7930 MG/KG;
LD50:(SCU,RAT) 5200 MG/KG; LD50:(I VN,RAT) 2600 MG/KG;
LD50:(ORAL,MUS) 4920 MG/KG; LD50:(IPR,MUS) 4450 MG/KG;
LD50:(SCU,MUS) 5060 MG/KG; LD50:(IVN,MUS) 2370 MG/KG - YACHDS
5,1502,1977. ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICA L
SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN
RTECS FOR COMPLETE INFORMATION.

Ecological:DATA NOT YET AVAILABLE.

Transport Information:CONTACT FLUKA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.

Federal Regulatory Information:TLV & SOURCE FOR NUISANCE PARTICULATES:
ACGIH TLV-TWA: 10 MG/M3. OSHA PEL: 8H TWA 15 MG/M3 TOTAL DUST; 8H
TWA 5 MG/M3, RESPIRABLE FRACTION. REVIEWS, STANDARDS & REGULATIONS:
OEL=MAK. OEL-RUSSIA: STEL 5 MG/M3 JAN 1993. NOHS 1974: HZD 80389;
NIS 17; TNF 1797; NOS 25; TNE 25710. NOES 1983: HZD 80389; NIS 24;
TNF 3706; NOS 48; TNE 115042; TFE 83784. EPA TSCA SECTION 8(B)
CHEMICAL INVENTORY. EPA TSCA S ECTION 8(D) UNPUBLISHED
HEALTH/SAFETY STUDIES. EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE,
DECEMBER 1998.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.